By Raymond B. Seymour, Tai Cheng (auth.), Raymond B. Seymour, Tai Cheng (eds.)
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Additional info for Advances in Polyolefins: The World’s Most Widely Used Polymers
C t t DN = nD-1. Table II. 14 Ultrasonic sound velocity, m/sec 1552 1489 t &From Reference 2. 26 Table III. 3308 1 11. 35 o. 3307 aFrom Reference 35. 027/m. CFrom References 14 and 33. dMolar refraction, Lorentz-Lorenz. eMagnetic susceptibility. length n-alkane; and (3) the expressions (Equations 1-6) found useful for n-alkaues and other homologs are useful also for polymer homologous pendant groups. Wunderlich32 referred to publications on seJeral series of homologous polymers: n-alkyl acrylates and methacrylates, n-alkyl styrenes, fluoroalkyl acrylates, vinyl esters, and N-n-alkyl acrylamides; the poly(1-alkenes) were not included.
Polymer Bulletin:-~, 9 (1982); M. Malanga and 0. Vogl, Polymer Bulletin, ~. 236 (1983), R. C. Anderson, C. L. Hoover, and o. Vogl, Macromolecules,~. · 222 (1978). 21 3. 4. 5. 22 H. V. Pechmann, Berichte der Deutsche Chemischer Gesellschaft, 32, (II) 2301 (III) 3681 (1899); Bamberger and Tschirner, Berichte der Deutsche Chemischer Gesellschaft, 33, 955 (1900); A. Nasini and G. Saini, Atti Acad. Scien. Torino:-90, 586 (1955); w. Lwovski, "Nitrenes," John Wiley (1970). "Fluoropolymers," A. , Wiley-Interscience, New York (1972).
In these instances theoretical molecular weights (DPn = [M 0 ]/[CHJCOORt]) and narrow 48 Fig. 5. 8 x 10-lM. molecular weight distributions were achieved at 100% conversions. Evidently, then, theoretical Mn, conversion, and Mw/Mn values can be obtained not only in polar diluents but under select conditions even in less polar media. A series of experiments have also been carried out by the use of HCCL3, however, the conversions were so low that experimentation with this solvent was discontinued (High or 100% conversions were obtained only in the presence of relatively high CuOAc concentrations).
Advances in Polyolefins: The World’s Most Widely Used Polymers by Raymond B. Seymour, Tai Cheng (auth.), Raymond B. Seymour, Tai Cheng (eds.)